L-Arginine & L-Citrulline Malate Blend Powder

L-Arginine & L-Citrulline Malate Blend Powder

Free-form amino acid blend · citrulline malate 2:1 with L-arginine base

A free-form amino acid blend of L-citrulline DL-malate 2:1 and L-arginine base, both fermentation-derived and vegan, supplied in bulk for pre-workout powders, shots and stick packs. Ratios built to your brief.

Specifications

Product typeDry free-form amino acid blend for pre-workout and pump-category formulations. Not a protein concentrate, isolate, hydrolysate or textured protein.
House compositionL-citrulline DL-malate 2:1 at 60% w/w with L-arginine base at 40% w/w; any split from 80:20 to 20:80 blended to order.
L-citrulline DL-malateCAS 54940-97-5 (trade CAS for both 1:1 and 2:1); L-citrulline CAS 372-75-8, MW 175.19; malic acid MW 134.09; theoretical citrulline in the 2:1 molar complex 72.3% w/w.
L-arginineCAS 74-79-3; C6H14N4O2; MW 174.20; USP assay 98.5-101.5% of C6H14N4O2 calculated on the dried basis.
Approved substitutionsL-arginine HCl (CAS 1119-34-2), L-arginine alpha-ketoglutarate 2:1 (CAS 5256-76-8), unsalted L-citrulline (CAS 372-75-8).
Appearance and solubilityWhite to off-white free-flowing crystalline powder, characteristic sour-bitter amino acid taste. Freely soluble in water; the malate acidity speeds wetting of arginine base.
Particle size100% through 40 mesh as standard. 80 mesh, granulated and instantised grades to order for stick-pack and effervescent formats.
Loss on dryingNMT 1.0% on the blend; L-arginine fraction NMT 0.5% (USP method, 105 °C). Hygroscopic — keep containers sealed.
Heavy metalsLead NMT 0.5 ppm; arsenic NMT 0.5 ppm; cadmium NMT 0.5 ppm; mercury NMT 0.1 ppm, by ICP-MS.
MicrobiologyTotal plate count NMT 1,000 cfu/g; yeast and mould NMT 100 cfu/g; E. coli and Salmonella absent per 25 g.
Origin, diet and allergensBoth amino acids by microbial fermentation of plant carbohydrate (Corynebacterium). Vegan. Free of milk, egg, soy, fish, crustacean, gluten and tree nut.
Non-animal declarationNot produced by keratin acid hydrolysis of hair or feather protein, a route still used industrially for L-arginine. Route is stated on every COA.
Sports complianceNo WADA prohibited-list substance added, consistent with FSSAI requirements for food for sportspersons. Third-party batch screening available on request.
Shelf life24 months from manufacture, unopened, below 25 °C and 60% RH, away from direct light.
HS code2106.90.99 as blended
Thovek supplies a bulk free-form amino acid blend built on two well-characterised chemistries: L-citrulline DL-malate (CAS 54940-97-5, quoted in trade for both the 1:1 and 2:1 complexes) and L-arginine base (CAS 74-79-3, C6H14N4O2, MW 174.20, USP assay 98.5-101.5% of C6H14N4O2 on the dried basis). Our house ratio is 60:40 citrulline malate to arginine, and we build any split from 80:20 to 20:80. L-arginine hydrochloride (CAS 1119-34-2), L-arginine alpha-ketoglutarate 2:1 (CAS 5256-76-8) and unsalted L-citrulline (CAS 372-75-8) are available as substitutions inside the same blend. Origin is the commercial question on this pair, and it is worth putting in writing. Both amino acids here are produced by microbial fermentation of plant-derived carbohydrate using Corynebacterium strains — not by keratin acid hydrolysis, a route still in industrial use for L-arginine that starts from animal hair and feather protein and cannot support a vegan declaration. Every lot ships with its manufacturing route stated on the certificate of analysis. The blend is vegan, and free of milk, egg, soy, fish, crustacean, gluten and tree nut. In formulation, the malate salt carries its own acidity and helps wet the arginine base, which is otherwise slow to dissolve at high load; buyers running effervescent or stick-pack formats usually take the instantised grade. Standard mesh is 100% through 40, with 80 mesh and granulated versions to order. L-arginine is the physiological substrate of nitric oxide synthase and L-citrulline is its urea-cycle precursor — that is the biochemistry brands formulate around in this category, and we state it as composition only. Thovek makes no health, performance or therapeutic claim for this material; substantiating any claim in your market is your responsibility.

Applications

Pre-workout powder blendsPump-category stick packsReady-to-mix amino shotsEffervescent performance tabletsEndurance capsule formulationsAmino acid drink basesContract manufacturer bulk supplyPrivate-label sports nutrition

Available grades

Food grade (FSSAI, FCC) as standard, with a USP-compliant L-arginine fraction on request. Non-GMO, vegan, Halal and Kosher certification available. Custom ratios, 80 mesh, granulated and instantised variants, and doping-control-screened lots to order.

Packaging: 25 kg net in HDPE-lined fibre drums or triple-laminate kraft bags with food-grade PE inner liner. 1 kg and 5 kg foil pouches for pilot and stability batches. Palletised 500-750 kg, shrink-wrapped and export-marked with lot, manufacturing and expiry dates.

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