Annatto Tocotrienols (Bixa orellana)

Annatto Tocotrienols (Bixa orellana)

Bixa orellana L. seed · 20–90% total tocotrienols, tocopherol-free

Tocopherol-free tocotrienol concentrate from annatto seed, running about 90% delta and 10% gamma tocotrienol. Oil grades 20-90% by HPLC, plus a spray-dried powder.

Specifications

Botanical identityBixa orellana L., family Bixaceae. Achiote, annatto, urucum or lipstick tree. Source material is the waxy red aril coating the seed inside the capsule
Delta-tocotrienolCAS 25612-59-3, C27H40O2, molecular weight 396.6 g/mol. The dominant isomer, reported at approximately 90% of total tocotrienol in annatto material
Gamma-tocotrienolCAS 14101-61-2, C28H42O2, molecular weight 410.6 g/mol. Reported at approximately 10% of total tocotrienol. Alpha and beta tocotrienol are not significant in annatto
Tocopherol statusCharacteristically tocopherol-free. This separates annatto tocotrienol from palm and rice bran tocotrienol complexes, which carry alpha-tocopherol alongside a mixed isomer profile
Pigment removedBixin and norbixin, the annatto colour bodies of E 160b, are removed during refining. The tocotrienol fraction is decolourised and deodorised, not a colouring extract
StandardisationTotal tocotrienols 20%, 50%, 70% and 90% by HPLC with fluorescence or UV detection. Delta and gamma isomers reported individually on the certificate of analysis
Carrier oilGrades below concentrate strength are standardised in a declared carrier: MCT, high-oleic sunflower or annatto seed oil. The carrier drives the allergen statement and tariff line
AppearanceClear to slightly viscous pale yellow to amber oil, bland to faintly characteristic in odour. Spray-dried powder: off-white to cream, free-flowing
Powder form20% to 25% total tocotrienol spray-dried on modified starch or gum acacia with an anticaking agent, for tablets, two-piece capsules and stick packs
SolubilityOil-soluble and practically insoluble in water; miscible with edible oils and with ethanol at ambient temperature. The powder disperses in water rather than dissolving
Vitamin E labellingTocotrienols are vitamin E vitamers but weaker in bioactivity than alpha-tocopherol, and US and EU vitamin E declarations rest on alpha-tocopherol. Declare by tocotrienol content
Typical purity limitsAcid value and peroxide value to the agreed limit; residual solvent to specification; lead NMT 1 ppm, arsenic NMT 0.5 ppm, cadmium NMT 0.5 ppm, mercury NMT 0.1 ppm
Allergen and diet statusVegan and vegetarian, plant-derived, non-GMO. No soy input, unlike mixed tocopherols from soybean deodoriser distillate. No palm, milk, egg, fish, crustacean, gluten or nut input
Shelf life and storage24 months from manufacture in unopened, filled, nitrogen-blanketed containers below 25 °C and away from light. Tocotrienol oils oxidise; reseal and re-blanket after part use
HS code2936.28 (29362800)
Annatto tocotrienols are the vitamin E fraction recovered from the seed of Bixa orellana L. (Bixaceae), the achiote or urucum tree, whose seeds are coated in a waxy red aril best known as the food colour annatto, E 160b. The colour bodies bixin and norbixin are removed during refining, leaving a decolourised, deodorised tocotrienol concentrate. What makes the annatto source distinctive is its isomer profile. Published annatto tocotrienol material runs at approximately 90% delta-tocotrienol (CAS 25612-59-3, C27H40O2, molecular weight 396.6) and 10% gamma-tocotrienol (CAS 14101-61-2, C28H42O2, MW 410.6), with no tocopherols present. Palm and rice bran tocotrienol complexes, by contrast, carry alpha-tocopherol alongside a mixed alpha, gamma and delta tocotrienol profile, which is why the two are not drop-in substitutes for one another. Thovek offers total tocotrienol at 20%, 50%, 70% and 90% by HPLC. Grades below concentrate strength are standardised in a declared carrier oil, typically MCT, high-oleic sunflower or annatto seed oil, and the carrier is named on the specification because it drives both the allergen statement and the tariff line the shipment travels on. A spray-dried powder at 20% to 25% total tocotrienol on modified starch or gum acacia is available for tablets, two-piece capsules and stick packs. All grades are oil-soluble and practically insoluble in water; the powder disperses rather than dissolves, which matters for beverage work where an emulsion or a dedicated dispersible system is needed. One labelling point matters commercially. Tocotrienols are vitamin E vitamers, but they are weaker in bioactivity than alpha-tocopherol, and vitamin E declarations in both the United States and the European Union are built on alpha-tocopherol. A tocotrienol concentrate is therefore normally declared by its tocotrienol content rather than counted toward a vitamin E daily value, and the wording should be confirmed market by market with your regulatory team. On allergens and diet status this is a plant-derived, vegan and vegetarian material with no soy input, which distinguishes it from mixed tocopherols recovered from soybean deodoriser distillate where soy is a declarable allergen, and with no palm, milk, egg, fish, crustacean, gluten or nut input. Tocotrienol oils oxidise, so lots ship in filled, nitrogen-blanketed, light-excluding containers and should be re-blanketed after part use.

Applications

Vitamin E supplement formatsSoftgel and liquid fillsTocopherol-free vitamin linesSports nutrition oil blendsNutricosmetic softgelsFunctional beverage emulsionsTablet and sachet powdersEdible oil fortification

Available grades

Total tocotrienol 20%, 50%, 70% and 90% by HPLC as an oil. Carrier options MCT, high-oleic sunflower or annatto seed oil, named on the specification. Spray-dried 20-25% tocotrienol powder on modified starch or gum acacia for solid dosage. Delta-enriched fraction to order where a higher delta share than the native profile is required. Kosher and halal certification available; organic-certified lots to order.

Packaging: Oil grades in 1 kg and 5 kg amber HDPE or lacquered tinplate containers, 20 kg HDPE jerricans and 190 kg lined steel drums, filled to minimise headspace and nitrogen-blanketed as standard. Spray-dried powder in 5 kg, 20 kg and 25 kg aluminium-foil laminate bags with LDPE inner, packed into fibre drums. Light-excluding outer packing on all formats.

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